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氢气压力对L80钢氢脆敏感性的影响规律

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  • 1. 中国石油集团工程技术研究院有限公司; 2. 中国石油天然气股份有限公司河北廊坊销售分公司; 3. 中国石油天然气集团公司吉林石化分公司炼油厂; 4. 中国石油大学(北京)石油工程学院; 5. 安科工程技术研究院(北京)有限公司
杨志文(1992- ),硕士研究生,中级工程师,主要从事油气田管道腐蚀与防控、失效分析等研究工作,电话:010-51390317,E - mail: yangzhw@ankosri.com

收稿日期: 2021-11-24

  修回日期: 2021-12-20

  录用日期: 2022-01-04

  网络出版日期: 2023-12-27

基金资助

中石油集团公司课题“气化炉建造关键技术研究与应用”;“盐穴氢储能密封完整性机理及控制方法研究”;“盐穴压缩空气与氢气储能工程关键技术研究”资助

Influence Law of Hydrogen Pressure on Hydrogen Embrittlement Sensitivity of L80 Steel

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  • 1. CNPC Engineering Technology R&D Company Limited, Beijing 102206, China; 2. Petro China Hebei Langfang Marketing Company, Langfang 065000, China; 3. Oil Refinery of Jilin Petrochemical Company, Petrochina, Jilin 132021, China; 4. College of Petroleum Engin - eering, China University of Petroleum, Beijing 102249, China; 5. Safetech Research Institute (Beijing) Co., Ltd., Beijing 102209, China

Received date: 2021-11-24

  Revised date: 2021-12-20

  Accepted date: 2022-01-04

  Online published: 2023-12-27

摘要

对L80钢在室温不同氢气压力下的氢脆敏感性进行了评价。通过缺口慢应变拉伸试验,结合断口分析,研究了3~12 MPa氢气压力下,L80钢的氢脆敏感性的变化规律。结果表明:在室温环境下,L80钢在5 MPa及以下氢气压力下应用时,无明显脆性;在8 MPa及以上氢气压力下应用时,具有明显脆性;在氢气压力3~12 MPa环境下,L80钢拉伸试样主断面中心位置微观形貌从韧窝形貌转变为韧窝形貌与解理形貌共存,边缘位置微观形貌从韧窝形貌向解理逐渐转变,断面收缩率变化率由16.19%逐渐增加至46.79%。随着氢气压力的增加,L80钢的塑性损失增加,断口表现出明显脆化特征,氢脆敏感性逐渐增加。

本文引用格式

董京楠, 刘奕杉, 张旭初, 王朝阳, 罗淼, 石贵元, 刘晓童, 杨志文, 陈迎锋 . 氢气压力对L80钢氢脆敏感性的影响规律[J]. 材料保护, 2022 , 55(3) : 53 -59 . DOI: 10.16577/j.issn.1001-1560.2022.0067

Abstract

The hydrogen embrittlement sensitivity of L80 steel under different hydrogen pressure at room temperature was evaluated this work. The variation rules of hydrogen embrittlement sensitivity of L80 steel at hydrogen pressure from 3 MPa to 12 MPa were studied by notch slow strain tensile test combined with fracture analysis. Results showed that L80 steel had no obvious brittleness at room temperature under hydrogen pressure of lower than 5 MPa, and yet had obvious brittleness under hydrogen pressure of more than 8 MPa. Under hydrogen pressure from 3 MPa to 12 MPa, the micro morpholgy at the center of the main section of L80 steel tensile sample changed from dimple morphology to coexistence of dimple morphology and cleavage morphology. The micro morphology at the edge gradually changed from dimple morphology to cleavage. In addition, the change rate of section shrinkage gradually increased from 16.19% to 46.79%. With the increase of hydrogen pressure, the plastic loss of L80 steel increased, the fracture showed obvious embrittlement characteristics, and the hydrogen embrittlement sensitivity gradually increased.
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