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堆焊层数对热丝脉冲TIG堆焊Inconel 625的腐蚀性能研究

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  • 1. 上海海隆石油管材研究所; 2. 上海海隆石油化工研究所
欧阳志英(1977-),博士,高级工程师,研究方向为适用于复杂环境新型钻具研发,E - mail:ouyangzsh@163.com

收稿日期: 2021-12-25

  修回日期: 2022-01-28

  录用日期: 2022-02-28

  网络出版日期: 2024-01-08

基金资助

上海市优秀技术带头人计划资助项目(19XD1430400)

Study on the Corrosion Performance of Hot Wire Pulsed TIG Surfacing Inconel 625 with Different Surfacing Layers

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  • 1. Shanghai Hilong Petroleum Tubular Goods Research Institute, Shanghai 200949, China;2. Shanghai Hilong Petrochemical Research Institute, Shanghai 200949, China

Received date: 2021-12-25

  Revised date: 2022-01-28

  Accepted date: 2022-02-28

  Online published: 2024-01-08

摘要

为了研究热丝脉冲TIG(惰性气体钨极保护焊)堆焊不同层数Inconel 625后堆焊层的腐蚀性能差异,在20钢基体表面分别堆焊单层和双层Inconel 625,通过电化学试验、晶间腐蚀试验和EDS成分分析,对不同层数堆焊层的腐蚀性能进行了对比分析。结果表明:其bode谱中双层堆焊的相位角为80°,单层堆焊和基材的相位角分别下降5°和20°,双层堆焊的阻抗模量与频率的斜率最大,其次是单层堆焊的,基材的最小;基材的容抗弧最小且存在Warbug扩散,双层堆焊的容抗弧最大,单层和双层堆焊较基材的自腐蚀电位分别提高了374.0 mV和392.0 mV,腐蚀电流密度分别下降约99.3%和99.8%,双层堆焊的点蚀电位较单层的提高了430 mV。晶间腐蚀试验后,堆焊层均未出现明显晶间腐蚀而表现为点蚀,双层堆焊的腐蚀失重约为单层的1/5,腐蚀沿柱状晶间贯穿。堆焊层间融合区以及与基体交界处的合金元素变化显著,层内分布均匀,双层堆焊的Fe元素含量低于单层堆焊的,具有更好的耐腐蚀性能。

本文引用格式

欧阳志英, 朱威, 任飙 . 堆焊层数对热丝脉冲TIG堆焊Inconel 625的腐蚀性能研究[J]. 材料保护, 2022 , 55(5) : 57 -62 . DOI: 10.16577/j.issn.1001-1560.2022.0125

Abstract

For studying the difference of corrosion performance of Inconel 625 surfacing layers obtained through hot wire pulse TIG (Tungsten Inert Gas Welding) surfacing, single - layer and double - layer coatings of Inconel 625 were applied on the surface of 20 steel through surfacing. The corrosion performance of surfacing layers with varying number was analyzed by electrochemical test, intergranular corrosion test and EDS component analysis. Results showed that in Bode diagram, the phase angle of double - layer surfacing was 80°, and that of the single - layer surfacing and substrate decreased by 5°and 20° respectively. The slope of impedance modulus and frequency of double - layer surfacing was the largest, followed by single - layer surfacing, and the minimum was the that of substrate. Additionally, the base material had Warbug diffusion and the smallest capacitance arc, while the double - layer surfacing had the largest capacitance arc. Self - corrosion potentials in single - layer and double - layer surfacing were 374.0 mV and 392.0 mV higher than that of the base material respectively, the corrosion current density decreased by about 99.3% and 99.8%, and the double - layer surfacing spot corrosion potential was 430 mV higher than that of the single - layer. After the intergranular corrosion test, no obvious intergranular corrosion appeared in the surfacing layer, but pitting corrosion was observed. Moreover, the weight loss of the double - layer surfacing corrosion was about 1/5 of the single - layer, and the corrosion penetrated along the columnar intergranular. The alloy elements in the fusion zone between layers and the interface with substrate changed significantly and distributed evenly within each layer. The Fe content of double - layer surfacing was lower than that of the single - layer surfacing, and thus the former had a better corrosion resistance.
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