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第14届全国青年表面工程学术会议专栏

常用固体润滑薄膜的辐照损伤研究进展

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  • 1西北工业大学先进润滑与密封材料研究中心; 2西北工业大学深圳研究院; 3香港城市大学机械工程系; 4中国科学院兰州化学物理研究所固体润滑国家重点实验室
周 青(1988-),博士,副教授,主要研究方向为极端工况防护涂层摩擦学,电话:13649204790,E-mail: zhouqing@nwpu.edu.cn;柴利强(1986-),博士,副研究员,主要研究方向为固体润滑薄膜材料,E-mail: chailiqiang423@licp.cas.cn;王 鹏(1978-),博士,研究员,主要研究方向为辐照环境与润滑材料相互作用,E-mail: pengwang@licp.cas.cn

收稿日期: 2024-08-29

  修回日期: 2024-10-11

  录用日期: 2024-10-15

  网络出版日期: 2025-05-23

基金资助

国家重点研发计划(2022YFB3809000);国家自然科学基金(52175188);广东省基础与应用基础研究基金联合基金(2024A1515012378);陕西省重点研究发展计划(2023-YB-434);核反应堆系统设计技术重点实验室基金

Research Progress on Radiation Damage of Commonly Used Solid Lubricating Films

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  • (1.Center of Advanced Lubrication and Seal Materials, Northwestern Polytechnical University, Xi’an 710072, China;2.Research & Development Institute of Northwestern Polytechnical University in Shenzhen, Shenzhen 518063, China;3.Department of Mechanical Engineering, City University of Hong Kong, Hong Kong 999077, China;4.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences, Lanzhou 730000, China)
ZHOU Qing(1988-), Ph.D., Associate Professor, Research Focus: Tribology of Protective Coatings Under Extreme Working Conditions, Tel.: 13649204790, E-mail: zhouqing@nwpu.edu.cn;CHAI Liqiang(1986-), Ph.D., Associate Researcher, Research Focus: Solid Lubricating Film Materials,E-mail: chailiqiang423@licp.cas.cn;WANG Peng(1978-), Ph.D., Researcher, Research Focus: Interaction Between Irradiation Environment and Lubricating Materials, E-mail: pengwang@licp.cas.cn

Received date: 2024-08-29

  Revised date: 2024-10-11

  Accepted date: 2024-10-15

  Online published: 2025-05-23

Supported by

National Key Research and Development Program of China (2022YFB3809000); Natural Science Foundation of China(52175188); Key Research and Development Program of Shaanxi Province (2023-YB-434); Guangdong Basic and AppliedBasic Research Foundation (2024A1515012378);Science and Technology on Reactor System Design Technology Laboratory

摘要

固体润滑薄膜以其优异的减摩抗磨性能、化学稳定性和高温稳定性在航空航天、核工业及机械制造等领域得到广泛应用。 然而,在太空、核反应堆等极端环境中,固体润滑薄膜易受辐照损伤而导致润滑性能失效。 本文首先介绍了3 类常用的固体润滑薄膜:二维层状润滑薄膜、碳基润滑薄膜和金属基润滑薄膜,并概述了它们在辐照和摩擦学方面的研究进展。 然后,提出了该领域目前存在的问题,并总结了该领域未来的发展方向。 最后,针对固体润滑薄膜在辐照环境下面临的挑战,从热退火处理、元素掺杂、多层复合膜结构设计、界面调控、晶粒细化5 方面展望了提高3 类常用的固体润滑薄膜抗辐照性能的措施。 该综述旨在帮助研究人员了解该领域研究的重要性及紧迫性,以推动具有优异抗辐照性能的固体润滑材料在苛刻辐照领域的发展应用,从而确保其机械部件在极端环境下的可靠性和稳定性。

本文引用格式

李金城, 石烨然, 华东鹏, 周青, 夏桥生, 柴利强, 王海丰, 王鹏 . 常用固体润滑薄膜的辐照损伤研究进展[J]. 材料保护, 2025 , 58(4) : 1 -16 . DOI: 10.16577/j.issn.1001-1560.2025.0055

Abstract

Solid lubricating thin film materials play a significant role in aerospace,the nuclear industry and mechanical engineering due to their excellent performance in reducing friction and wear, as well as their good chemical stability and resistance to high temperatures.However,these materials face the challenge of radiation damage in extreme environments, such as space and high-temperature nuclear reactors, which can lead to a significant decrease in material performance, thus affecting their reliability and durability in practical applications.In this paper,three main types of solid lubricating thin films were first introduced, which included two-dimensional layered lubricating films, carbon-based lubricating thin films, and metal-based lubricating thin films.Two-dimensional layered lubricating films,such as graphene and transition metal dichalcogenides,showed ultra-low friction coefficients due to their single or few layers of atomic thickness, achieving a “superlubricating”effect.These materials were not only recognized for their excellent tribological properties but also for their exceptional mechanical strength and chemical inertness, making them potentially valuable for applications in harsh environments, such as nuclear radiation.Carbon-based lubricating thin films, such as hydrogenated amorphous carbon films, graphite, and fullerenes, maintained their lubricating performance in adverse environments due to their diverse allotropes of carbon and physical and chemical properties.Metal-based lubricating thin films, especially silver-based films, were shown to exhibit good lubricating performance in high-temperature and irradiation environments when combined with other solid lubricants.Secondly, the challenges faced by solid lubricating films in irradiation environments were summarized, and an outlook on future research directions in the field of radiation resistance of commonly used solid lubricating films was provided.Five strategies to enhance the radiation resistance of solid lubricating films were further explored:First,thermal annealing treatments were conducted,after which two-dimensional layered lubricating films,such as MoS2,were shown to exhibit fewer defects when subjected to irradiation.Second,doping with radiation-resistant elements was proposed;for example,chromium was introduced into carbon-based lubricating films,effectively improving the tribological stability and durability of DLC materials.The third strategy involved designing multilayer film structures that captured defect atoms through heterointerfaces, effectively improving the tribological performance of metal-based lubricating films.The fourth strategy was to regulate the interfacial area,where the crystal/amorphous interface was found to have higher radiation tolerance.The fifth strategy was to refine the grain size, as grain refinement was shown to effectively improve the radiation resistance of metal-based lubricating films.In conclusion,solid lubricating thin films have great application potential in extreme environments such as space exploration and the nuclear industry.Future research will focus on deeply understanding the impact of irradiation on solid lubricating thin films and developing new strategies to improve their radiation resistance, ensuring that these materials can maintain their excellent lubricating performance in extreme environments.
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