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电镀NiCoCe合金层的制备及耐蚀性能研究

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  • 1中国石化管道储运有限公司科技研发中心;2中国石油大学(华东)材料科学与工程学院

网络出版日期: 2025-07-10

Study on the Preparation and Corrosion Resistance of Electroplated NiCoCe Alloy Coatings

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  • 1. Science and Technology R&D Center of Sinopec Pipeline Storage and Transportation Co., Ltd., Xuzhou 221008, China; 2. School of Materials Science and Engineering, China University of Petroleum, Qingdao 266580, China

Online published: 2025-07-10

摘要

镍镀层具有较好的耐蚀性和耐磨性,单纯的镍镀层易存在孔隙、晶粒粗大等缺陷,在镀镍时加入少量稀土元素可以显著提高镀层的性能。为此,通过改变电镀液成分和电流密度,在Q235基底上电镀形成一系列NiCoCe合金层,通过浸泡试验及电化学试验评价表面处理前后耐蚀性能的变化。结果表明:添加0~0.4 g/L Ce元素可以通过细化晶粒有效增强镀层的耐蚀性,当电流密度小于0.04 A/cm2时,电流密度的增加可以使镀层中的晶粒细化,提高镀层的致密性和耐腐蚀性。当Ce元素的添加量为0.4 g/L,电流密度为0.03 A/cm2,电镀温度为50 ℃时,试验效果最佳。

本文引用格式

彭云超, 马凯军, 贾犇, 董愿能 . 电镀NiCoCe合金层的制备及耐蚀性能研究[J]. 材料保护, 2021 , 54(8) : 101 . DOI: 10.16577/j.cnki.42-1215/tb.2021.08.018

Abstract

The Ni plating has good corrosion resistance and wear resistance. However, the pure Ni plating is prone to undergo the defect of porosity and coarse grains, the performance of which can be apparently improved by adding a small amount of rare earth elements during nickel plating. Hence, a series of NiCoCe alloy layers was formed on the Q235 substrate by electroplating and changing the composition of the plating solution and the current density, and the changes in corrosion resistance before and after the surface treatment were evaluated by immersion tests and electrochemical experiments. Result showed that the addition of 0~0.4 g/L Ce element could effectively enhance the corrosion resistance of the coating by refining the grains. When the current density was less than 0.04 A/cm2, the increase in current density could refine the grains in coatings and improve compactness and corrosion resistance. When the added amount of Ce element was 0.4 g/L, the current density was 0.03 A/cm2 and the plating temperature was 50 ℃, the as-prepared coating obtained the optimal experimental results.
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