纳米Nd2O3 对TC11 钛合金微弧氧化层耐磨性及高温抗氧化性能的影响

程赵辉, 杨 巍, 张 勇, 石小倩, 饶模松

doi:10.16577/j.issn.1001-1560.2023.0159

材料保护 >

2023 , Vol. 56 >Issue 7: 38 - 46

DOI: https://doi.org/10.16577/j.issn.1001-1560.2023.0159

微弧氧化及液态等离子电解技术专栏

纳米Nd₂O₃ 对TC11 钛合金微弧氧化层耐磨性及高温抗氧化性能的影响

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西安工业大学材料与化工学院，陕西西安 710021

杨巍(1981-)，博士，教授，研究方向为金属表面改性与强化，E-mail:yangwei_smx＠163.com

收稿日期: 2023-02-03

修回日期: 2023-03-02

录用日期: 2023-04-01

网络出版日期: 2023-08-23

基金资助

国家自然科学基金(52071252)资助

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Effect of Nano Nd₂O₃ on the Wear Resistance and High Temperature Oxidation Resistance of Micro-Arc Oxidation Coating on TC11 Titanium Alloy

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School of Materials and Chemical Engineering，Xi’an Technological University，Xi’an 710021，China

Received date: 2023-02-03

Revised date: 2023-03-02

Accepted date: 2023-04-01

Online published: 2023-08-23

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摘要

为了提高TC11 钛合金耐磨性及高温抗氧化性，通过添加不同浓度Nd2O3颗粒制备了Nd2O3颗粒掺杂的微弧氧化层。采用扫描电镜、X 射线衍射仪等研究了Nd2O3浓度对TC11 钛合金表面微弧氧化层微观结构、物相组成的影响，并评价了涂层的耐磨性与高温抗氧化性能。结果表明:添加Nd2O3颗粒后，膜层表面的微孔数量减少，膜层物相以金红石型TiO2和锐钛矿型TiO2为主，随着Nd2O3浓度的增加，Nd 元素在膜层中的含量逐渐增加，膜层厚度先增大后减小；在Nd2O3浓度为1 g/L 时，所制备的微弧氧化层综合性能最佳，膜层平均厚度8.68 μm，磨损失重0.43 mg，磨痕宽度598.04 μm，高温氧化增重0.139 mg/cm2。与TC11 钛合金基体和未添加Nd2O3颗粒的试样相比，添加1 g/L Nd2O3后微弧氧化层的高温抗氧化性得到显著改善，耐磨性较未添加Nd2O3颗粒时的下降。

关键词： TC11; 微弧氧化; Nd2O3颗粒; 耐磨性; 高温抗氧化性

本文引用格式

程赵辉, 杨巍, 张勇, 石小倩, 饶模松 . 纳米Nd₂O₃ 对TC11 钛合金微弧氧化层耐磨性及高温抗氧化性能的影响[J]. 材料保护, 2023 , 56(7) : 38 -46 . DOI: 10.16577/j.issn.1001-1560.2023.0159

Abstract

In order to improve the wear resistance and high temperature oxidation resistance of TC11 titanium alloy，Nd2O3 particle-doped micro-arc oxidation coatings were prepared by adding different concentrations of Nd2O3 particles.The effect of Nd2O3 concentration on the microstructure and phase composition of micro-arc oxidation coatings on TC11 titanium alloy was studied by scanning electron microscope and X-ray Diffractometer.Meanwhile，the wear resistance and high temperature oxidation resistance of the coating was evaluated.Results showed that after adding Nd2O3 particles，the number of micropores on the surface of the coating decreased，and the coating phase was mainly rutile TiO2 and anatase TiO2.With the increase of Nd2O3 concentration，the content of Nd element in the coating gradually increased，and the coating thickness first increased and then decreased.When the concentration of Nd2O3 was 1 g/L，the comprehensive performance of the prepared micro-arc oxidation coating was the best，which possessed the average thickness of 8.68 μm，the wear loss of 0.43 mg，the wear scar width of 598.04 μm，and the high temperature oxidation weight gain of 0.139 mg/cm2.Compared with the TC11 titanium alloy and the sample without adding Nd2O3 particles，the high temperature oxidation resistance of the micro-arc oxidation coating was significantly improved after adding 1 g/L Nd2O3 particles，and the wear resistance decreased compared with that without adding Nd2O3 particles.

Key words： TC11; micro-arc oxidation; Nd₂O₃particle; wear resistance; high temperature oxidation resistance

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