人工海水环境中不同偏压制备的(TiNbMoZrW)C涂层的摩擦腐蚀性能研究

吴丽欣, 刘鑫宇, 王军军

doi:10.16577/j.issn.1001-1560.2023.0182

材料保护 >

2023 , Vol. 56 >Issue 8: 18 - 27

DOI: https://doi.org/10.16577/j.issn.1001-1560.2023.0182

高熵合金涂层专栏

人工海水环境中不同偏压制备的(TiNbMoZrW)C涂层的摩擦腐蚀性能研究

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重庆理工大学材料科学与工程学院，重庆 400050

王军军(1986-)，博士，教授，硕士研究生导师，主要研究方向为薄膜材料的理论模拟与设计，材料表面科学与工程。E-mail:wangjunjun＠cqut.edu.cn

收稿日期: 2023-02-21

修回日期: 2023-03-12

录用日期: 2023-04-15

网络出版日期: 2023-08-25

基金资助

重庆市基础研究和前沿技术研究计划(cstc2021jcy-msxmX0396)；重庆市技术创新与应用开发项目(cstc2019jscxfxydX0046)资助

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Study on Tribocorrosion Performance of the (TiNbMoZrW)C Coatings Prepared under Different Bias in Artificial Seawater

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College of Materials and Engineering，Chongqing University of Technology，Chongqing 400050，China

Received date: 2023-02-21

Revised date: 2023-03-12

Accepted date: 2023-04-15

Online published: 2023-08-25

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摘要

多主元碳化物涂层作为腐蚀防护领域极具前景的候选材料，具有低摩擦系数、低磨损率和良好的耐腐蚀性能，但对其摩擦腐蚀性能的相关研究较少。为促进多主元碳化物涂层在海水环境中的应用，利用反应磁控溅射技术，通过调控基底偏压制备了(TiNbMoZrW)C 涂层。通过X 射线衍射仪、X 射线光电子能谱仪、原子力显微镜、扫描电子显微镜、维氏硬度计和纳米压痕仪对(TiNbMoZrW)C 涂层的微观结构和力学性能进行了系统表征，并分析了涂层在人工海水中的电化学特性和摩擦腐蚀性能。结果表明:随着脉冲偏压从0 增加到-800 V，制备的(TiNbMoZrW)C 涂层的残余压应力、硬度和弹性模量均呈现增大趋势。-800 V 偏压沉积的涂层具有最大硬度(25.9 GPa)和弹性模量(356.34 GPa)，良好的抗裂性和耐腐蚀性，在人工海水和空气中具有最低的磨损率，分别为1.00×10-7和2.28×10-7mm3/(N·m)。增加偏压有利于改善(TiNbMoZrW)C 涂层在人工海水中的摩擦腐蚀性能。

关键词： (TiNbMoZrW)C 涂层; 碳化物; 偏压; 力学性能; 摩擦腐蚀性能

本文引用格式

吴丽欣, 刘鑫宇, 王军军 . 人工海水环境中不同偏压制备的(TiNbMoZrW)C涂层的摩擦腐蚀性能研究[J]. 材料保护, 2023 , 56(8) : 18 -27 . DOI: 10.16577/j.issn.1001-1560.2023.0182

Abstract

As a kind of promising candidate materials in the field of corrosion protection，the multi-component carbide coatings have low friction coefficient，low wear rate and good corrosion resistance，but there are few studies on the tribocorrosion performance.In order to promote the application of the multi-component carbide coatings in seawater environment，the (TiNbMoZrW)C coatings were prepared via reactive magnetron sputtering under various pulse bias voltages.The microstructures and the mechanical properties of the (TiNbMoZrW)C coatings were systematically characterized by X-ray diffraction，X-ray photoelectron spectroscopy，atomic force microscope，scanning electron microscope，Vickers indentation and nano-indentation experiment.In addition，the electrochemical characteristics and friction and corrosion properties of coatings in artificial seawater were analyzed.Results showed that the pressure residual stress，hardness and elastic modulus of the prepared (TiNbMoZrW)C coating showed an increasing trend when the pulse bias increased from 0 to -800 V.The (TiNbMoZrW)C coating deposited under -800 V pulse bias had the maximum hardness (25.9 GPa) and the maximum elastic modulus (365.34 GPa)，excellent crack and corrosion resistance，which exhibited the lowest wear rate in artificial seawater [1.00×10-7mm3/(N·m)] and air [2.28×10-7mm3/(N·m)].Meanwhile，the application of higher pulse bias was beneficial to improve the tribocorrosion performance of the (TiNbMoZrW)C coatings in artificial seawater.

Key words： (TiNbMoZrW)C high-entropy alloy coating; carbide; bias; mechanical properties; tribocorrosion performance

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