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粗糙度对微弧氧化/类金刚石复合涂层结构及性能的影响

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  • (1. 四川轻化工大学材料科学与工程学院, 四川 自贡 643000; 2. 材料腐蚀与防护四川省重点实验室, 四川 自贡 643000; 3. 中国科学院兰州化学物理研究所固体润滑国家重点实验室, 甘肃 兰州 730000)

崔学军(1978-),教授,博士,研究方向为金属腐蚀/磨损与表面新技术,E-mail:cxj_2046@163.com

收稿日期: 2022-04-20

  修回日期: 2022-05-10

  录用日期: 2022-06-01

  网络出版日期: 2023-12-23

基金资助

四川省自然科学基金项目(2022NSFC0330); 材料腐蚀与防护四川省重点实验室开放基金项目(2020CL09); 盐都创新领军人才项目资助

Effects of Roughness on the Structure and Properties of Micro Arc Oxidation / Diamond ⁃Like Composite Coatings

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  • (1. School of Materials Science and Engineering, Sichuan University of Science and Engineering, Zigong 643000, China; 2. Material Corrosion and Protection Key Laboratory of Sichuan Province, Zigong 643000, China; 3. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China)

Received date: 2022-04-20

  Revised date: 2022-05-10

  Accepted date: 2022-06-01

  Online published: 2023-12-23

摘要

为了研究微弧氧化(MAO)涂层表面微结构对MAO/类金刚石碳基薄膜(DLC)复合涂层结构及性能的影响,通过调控电压在镁合金表面制备不同粗糙度的MAO涂层,再通过非平衡磁控溅射技术构筑MAO/DLC复合涂层。利用扫描电子显微镜(SEM)、电子能谱分析(EDS)、表面粗糙度仪、划痕仪、摩擦磨损测试仪和电化学工作站,研究了涂层的微结构、粗糙度、厚度、力学性能、摩擦磨损性能和耐蚀性能。结果表明:当MAO涂层粗糙度从0.19μm逐渐增加到0.57μm时,MAO涂层的表面孔隙率从9.429%增加到12.924%,摩擦系数从0.53增大至0.66,自腐蚀电位从-1.571 V负移至-1.595 V;表面沉积3.1μm厚DLC膜的粗糙度从0.22μm增加到0.58μm,表面孔隙率从1.553%增加到6.074%,摩擦系数从0.24增大至0.45,磨损率由2.01×10-5 mm3/(N·m)增加到8.41×10-5 mm3/(N·m),自腐蚀电位从-1.547 V正移至-1.486 V。复合涂层的界面结合强度从5.51 N增大至7.89 N,结合力增强了43%。MAO涂层的表面粗糙度决定了其与DLC涂层的界面结合强度,增大表面粗糙度能显著提高复合涂层界面结合强度,但同时增大了表面孔隙率,从而导致MAO涂层及其复合涂层的腐蚀/磨损防护性能变差。

本文引用格式

傅文恺, 崔学军, 杨帆, 杨巧玲, 张广安 . 粗糙度对微弧氧化/类金刚石复合涂层结构及性能的影响[J]. 材料保护, 2022 , 55(10) : 1 -10 . DOI: 10.16577/j.issn.1001-1560.2022.0268

Abstract

In order to study the effects of the surface microstructure of micro arc oxidation (MAO) coating on the structure and properties of MAO/ diamond like carbon (DLC) film composite coating, MAO coatings with different roughnesses were prepared on the surface of magnesi um alloy by voltage regulation, and then MAO/ DLC composite coatings were constructed by unbalanced magnetron sputtering. The microstructure, roughness, thickness, mechanical properties, friction and wear properties and corrosion resistance of the coatings were studied by scanning electron microscope (SEM), electron energy dispersive spectroscopy (EDS), surface roughness tester, scratch tester, friction and wear tester and electrochemical workstation. Results showed that when the roughness of MAO coating increased gradually from 0.19 μm to 0.57μ, the surface porosity of MAO coating increased from 9.429% to 12.924%, the friction coefficient increased from 0.53 to 0.66, and the selfcorrosion potential shifted negatively from -1.571 V to -1.595 V. Moreover, the roughness of 3.1 μm thick DLC film deposited on the surface increased from 0.22 μm to 0.58 μm. The surface porosity increased from 1.553% to 6.074%, the friction coefficient increased from 0.24 to 0.45, the wear rate increased from 2.01×10-5 mm3/(N·m) to 8.41×10-5 mm3/(N·m), and the self corrosion potential shifted positively from -1.547 V to -1.486 V. Meanwhile, the interfacial bonding strength of the composite coating increased from 5.51 N to 7.89 N, and the bonding force increased by 43%. Overall, the surface roughness of MAO coating determined the interface bonding strength with DLC coating. Increasing the surface roughness could significantly improve the interface bonding strength of composite coating, however it would also increase the surface porosity, resulting in the deterioration of corrosion / wear protection performance of MAO coating and its composite coating.

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