粗糙度对微弧氧化/类金刚石复合涂层结构及性能的影响
(1. 四川轻化工大学材料科学与工程学院, 四川 自贡 643000; 2. 材料腐蚀与防护四川省重点实验室, 四川 自贡 643000; 3. 中国科学院兰州化学物理研究所固体润滑国家重点实验室, 甘肃 兰州 730000)
收稿日期: 2022-04-20
修回日期: 2022-05-10
录用日期: 2022-06-01
网络出版日期: 2023-12-23
基金资助
四川省自然科学基金项目(2022NSFC0330); 材料腐蚀与防护四川省重点实验室开放基金项目(2020CL09); 盐都创新领军人才项目资助
Effects of Roughness on the Structure and Properties of Micro Arc Oxidation / Diamond ⁃Like Composite Coatings
(1. School of Materials Science and Engineering, Sichuan University of Science and Engineering, Zigong 643000, China; 2. Material Corrosion and Protection Key Laboratory of Sichuan Province, Zigong 643000, China; 3. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China)
Received date: 2022-04-20
Revised date: 2022-05-10
Accepted date: 2022-06-01
Online published: 2023-12-23
傅文恺, 崔学军, 杨帆, 杨巧玲, 张广安 . 粗糙度对微弧氧化/类金刚石复合涂层结构及性能的影响[J]. 材料保护, 2022 , 55(10) : 1 -10 . DOI: 10.16577/j.issn.1001-1560.2022.0268
In order to study the effects of the surface microstructure of micro arc oxidation (MAO) coating on the structure and properties of MAO/ diamond ⁃like carbon (DLC) film composite coating, MAO coatings with different roughnesses were prepared on the surface of magnesi⁃ um alloy by voltage regulation, and then MAO/ DLC composite coatings were constructed by unbalanced magnetron sputtering. The microstructure, roughness, thickness, mechanical properties, friction and wear properties and corrosion resistance of the coatings were studied by scanning electron microscope (SEM), electron energy dispersive spectroscopy (EDS), surface roughness tester, scratch tester, friction and wear tester and electrochemical workstation. Results showed that when the roughness of MAO coating increased gradually from 0.19 μm to 0.57μm, the surface porosity of MAO coating increased from 9.429% to 12.924%, the friction coefficient increased from 0.53 to 0.66, and the self⁃corrosion potential shifted negatively from -1.571 V to -1.595 V. Moreover, the roughness of 3.1 μm thick DLC film deposited on the surface increased from 0.22 μm to 0.58 μm. The surface porosity increased from 1.553% to 6.074%, the friction coefficient increased from 0.24 to 0.45, the wear rate increased from 2.01×10-5 mm3/(N·m) to 8.41×10-5 mm3/(N·m), and the self ⁃ corrosion potential shifted positively from -1.547 V to -1.486 V. Meanwhile, the interfacial bonding strength of the composite coating increased from 5.51 N to 7.89 N, and the bonding force increased by 43%. Overall, the surface roughness of MAO coating determined the interface bonding strength with DLC coating. Increasing the surface roughness could significantly improve the interface bonding strength of composite coating, however it would also increase the surface porosity, resulting in the deterioration of corrosion / wear protection performance of MAO coating and its composite coating.
Key words: magnesium alloy; micro arc oxidation; diamond-like carbon film; roughness; corrosion; wear
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