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某气田污水储罐穿孔失效机理研究

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  • 1. 西安石油大学材料科学与工程学院西安市高性能油气田材料重点实验室; 2. 长庆油田分公司第四采油厂
董 会(1981-),博士,副教授,主要研究方向为金属的腐蚀与防护,E - mail:donghuihyy@163.com

收稿日期: 2021-11-18

  修回日期: 2021-12-31

  录用日期: 2022-01-11

  网络出版日期: 2024-01-09

基金资助

陕西省自然科学基金(2020JM - 540);西安石油大学《材料科学与工程》省级优势学科(YS37020203);西安石油大学研究生创新与实践能力培养计划资助(YCS18212049)

Research on Perforation Failure Mechanism of Sewage Tank in a Gas Field

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  • 1. Xi’an Key Laboratory of High Performance Oil and Gas Field Materials, Xi’an Shi you University School of Materials Science and Engineering, Xi’an 710065, China;2. The Fourth Oil Production Plant of Changqing Oil Field Branch, Yinchuan 750000, China

Received date: 2021-11-18

  Revised date: 2021-12-31

  Accepted date: 2022-01-11

  Online published: 2024-01-09

摘要

某气田污水储罐在服役过程中发生穿孔泄漏。为分析穿孔原因,明确污水储罐常见穿孔部位的临界壁厚,利用显微硬度计、万能试验机、金相显微镜、扫描电子电镜(SEM)、能谱仪(EDS)和X射线衍射仪(XRD)对储罐理化性能、穿孔特征、腐蚀产物形貌及成分进行分析。结果表明:材质的理化性能符合要求;腐蚀产物疏松,以Fe2O3为主,夹杂少量FeS;腐蚀坑由储罐内壁向外壁发展,穿孔时腐蚀坑深度约为2.6 mm。因此,储罐穿孔机理与过程为水与腐蚀性介质渗入到膜层与储罐内壁之间发生氧腐蚀为主,SRB腐蚀为辅的腐蚀,在储罐内壁形成局部腐蚀坑。腐蚀坑深度达到储罐初始壁厚的65%时,坑底应力水平超过储罐抗内压强度,形成穿孔,造成储罐泄漏。

本文引用格式

周勇, 边颖帅, 曹亚雄, 董会, 周攀虎, 宋荣杰 . 某气田污水储罐穿孔失效机理研究[J]. 材料保护, 2022 , 55(5) : 200 -205 . DOI: 10.16577/j.issn.1001-1560.2022.0146

Abstract

A perforated leakage occurred in a gas field sewage storage tank in service. In order to analyze the cause of the perforation and to clarify the critical wall thicknesses of the common perforated points of the sewage storage tank, the micro hardness tester, universal testing machine, metallurgical microscope, scanning electron microscope (SEM), energy spectrometer (EDS) and X - ray diffraction (XRD) were used to analyze the physical and chemical properties of the storage tank, perforation characteristics, the morphology and composition of corrosion products. Results showed that the physical and chemical properties of the material met the requirements; the corrosion products were loose, mainly containing Fe2O3 and having a small amount of FeS. The corrosion pit developed from the inner wall of the storage tank to the outer wall, and the depth of the corrosion pit was about 2.6 mm. Therefore, the perforation mechanism and process of the storage tank could be destribed as follow: the water and corrosive medium penetrated between the layer and the inner wall of the storage tank, leading to an oxygen corrosion (the main corrosion) and a SRB corrosion (the auxiliary corrosion), and as a result, local corrosion pits formed on the inner wall of the storage tank. When the depth of the corrosion pit reached 65% of the initial wall thickness of the storage tank, the stress level at the bottom of the pit exceeded the internal pressure resistance of the storage tank, resulting in a perforation leakage of the storage tank.
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