镍基表面石墨烯自修复生长及摩擦性能研究

吕通发, 曹 阳, 何永春, 吕 超, 鲁继超, 于世奇, 吴 涛, 牟 鑫, 强 豪, 叶晓慧

doi:10.16577/j.issn.1001-1560.2023.0014

材料保护 >

2023 , Vol. 56 >Issue 1: 88 - 93

DOI: https://doi.org/10.16577/j.issn.1001-1560.2023.0014

工艺探讨

镍基表面石墨烯自修复生长及摩擦性能研究

展开

1. 国网内蒙古东部电力有限公司兴安供电公司，内蒙古乌兰浩特 137400；2. 国网内蒙古东部电力有限公司，内蒙古呼和浩特 010000；3. 陕西科技大学材料科学与工程学院，陕西西安 710021

叶晓慧(1987-)，副教授，博士研究生，研究方向为石墨烯触头材料，E-mail:yexiaohui＠sust.edu.cn

收稿日期: 2022-07-13

修回日期: 2022-08-16

录用日期: 2022-09-07

网络出版日期: 2023-07-25

基金资助

国家自然科学基金(61705125)资助；

收起

Study on Self-Healing Growth and Friction Properties of Graphene on Nickel-Based Surface

Expand

1. Xing’an Power Supply Company， State Grid Inner Mongolia Eastern Power Co.， Ltd.， Ulanhot 137400， China；2. State Grid Inner Mongolia Eastern Power Co.， Ltd.， Hohhot 010000， China；3. School of Materials Science and Engineering， Shaanxi University of Science and Technology， Xi’an 710021， China

Received date: 2022-07-13

Revised date: 2022-08-16

Accepted date: 2022-09-07

Online published: 2023-07-25

Fold

摘要

针对石墨烯纳米级厚度对基底保护耐久性不足的问题，通过热处理方法研究了镍基表面石墨烯膜破损后再次生长的自修复工艺。通过结构与形貌的表征表明，在热处理温度为700℃、保温时间5 min条件下，石墨烯可以再次生长，修复破损表面。摩擦实验测试结果显示，再生长的石墨烯薄膜其摩擦系数为0.05,较原始镍表面的降低了50%。同时探索了其再生长的机理，清晰阐述了石墨烯再生长的驱动力。研究成果可为石墨烯自修复领域提供实验基础和理论解释。

关键词： 石墨烯; 自修复生长; 摩擦性能; 镍基体

本文引用格式

吕通发, 曹阳, 何永春, 吕超, 鲁继超, 于世奇, 吴涛, 牟鑫, 强豪, 叶晓慧 . 镍基表面石墨烯自修复生长及摩擦性能研究[J]. 材料保护, 2023 , 56(1) : 88 -93 . DOI: 10.16577/j.issn.1001-1560.2023.0014

Abstract

To solve the problem of insufficient durability of graphene film with nano-scale thickness in substrate protection， the self-healing process referring to the re-growth of graphene film after damage on a nickel-based surface was studied by heat treatment method. The characterization of microstructure and morphology showed that the graphene could grow again and repair the damaged surface under the conditions of a heat treatment temperature of 700 ℃and a holding time of 5 min. The results of friction test showed that the friction coefficient of the regrown graphene film was 0.05， which was 50%lower than that of the original nickel surface. Meantime， the mechanism of graphene regrowth was explored， and the driving force of graphene regrowth was described clearly. Generally， this research achievements provided experimental basis and theoretical explanation for graphene self-healing field.

Key words： graphene; self-healing growth; friction performance; nickel substrate

参考文献

[ 1] HOLMBERG K， ANDERSSON P， ERDEMIR A. Global energy consumption due to friction in passenger cars[J]. Tribology International， 2012， 47: 221-234.

[ 2] 吴浩，夏延秋，吴礼宁，等. 磁控溅射碳/铜复合涂层在脂润滑下的载流摩擦学性能研究[J]. 材料保护，2021， 54(11): 10-14.WU H， XIA Y Q， WU L N， et al. Study on Current-Carrying Tribological Properties of Magnetron Sputtered Carbon/Copper Composite Coatings under Grease Lubrication[J].Materials Protection， 2021， 54(11): 10-14.

[ 3] HOLMBERG K， ERDEMIR A. The impact of tribology on energy use and CO2 emission globally and in combustion engine and electric cars[J]. Tribology International， 2019，135: 389-396.

[ 4] 段昭宇，李长生，开绍森，等. 镀镍石墨/NiCrW 合金复合材料的微观组织和摩擦学性能[J]. 材料保护， 2021，54(4): 1-6.DUAN Z Y， LI C S， KAI S S， et al. Microstructures and Wear Behavior of Nickel - Coated Graphite/NiCrW Alloy Composite[J]. Materials Protection， 2021， 54(4): 1-6.

[ 5] 郑泉水，欧阳稳根，马明，等. 超润滑:“零”摩擦的世界[J]. 科技导报， 2016， 34(9): 12-26.ZHENG Q S，OUYANG W G， MA M， et al. Super lubrication:A world of "zero" friction[J]. Science and Technology Review， 2016， 34(9): 12-26.

[ 6] QU C， SHI S， MA M， et al. Rotational instability in superlubric joints[J]. Physical Review Letters，2019，122(24):246 101.

[ 7] HOD O， MEYER E， ZHENG Q， et al. Structural superlubricity and ultralow friction across the length scales[J]. Nature， 2018， 563(7 732): 485-492.

[ 8] PTAK F， ALMEIDA C M， PRIOLI R. Velocity-dependent friction enhances tribomechanical differences between monolayer and multilayer graphene[J]. Scientific Reports，2019，9(1): 1-9.

[ 9] WU P， LI X， ZHANG C， et al. Self-assembled graphene film as low friction solid lubricant in macroscale contact[J].ACS Applied Materials ＆ Interfaces， 2017， 9 (25):21 554-21 562.

[10] BAO T， WANG Z， ZHAO Y， et al. Long-term stably dispersed functionalized graphene oxide as an oil additive[J].RSC Advances， 2019， 9(67): 39 230-39 241.

[11] DAI B， FU L， ZOU Z， et al. Rational design of a binary metal alloy for chemical vapour deposition growth of uniform single-layer graphene[J]. Nature Communications，2011，2(1): 1-6.

[12] LI X， CAI W， COLOMBO L， et al. Evolution of graphene growth on Ni and Cu by carbon isotope labeling[J]. Nano Letters， 2009， 9(12): 4 268-4 272.

[13] CHEN Y P， YU Q. Graphene rolls off the press[J]. Nature Nanotechnology， 2010， 5(8): 559-560.

[14] BAE S， KIM H， LEE Y， et al. Roll-to-roll production of 30-inch graphene films for transparent electrodes[J]. Nature Nanotechnology， 2010， 5(8): 574-578.

[15] BUBNOVA O. A decade of R2R graphene manufacturing[J]. Nature Nanotechnology， 2021， 16(10): 1 050.

[16] 张朝华，付磊，张艳锋，等. 石墨烯催化生长中的偏析现象及其调控方法[J]. 化学学报， 2013，71(3):308-322.ZHANG Z H， FU L， ZHANG Y F， et al. Segregation Phenomenon and Its Control in the Catalytic Growth of Graphene[J]. Acta Chimica Sinica， 2013，71(3):308-322.

[17] 魏博远. 高熵合金基底CVD 石墨烯生长规律及微观机理研究[D]. 哈尔滨: 哈尔滨工业大学， 2020.WEI B Y. Research on the microscopic mechanism of graphene growth by high entropy alloy based CVD[D]. Harbin: Harbin Institute of Technology， 2018.

[18] YE X， LONG J， LIN Z， et al. Direct laser fabrication of large-area and patterned graphene at room temperature[J].Carbon， 2014， 68: 784-790.

[19] YE X， LIN Z， ZHANG H， et al. Protecting carbon steel from corrosion by laser in situ grown graphene films[J].Carbon， 2015， 94: 326-334.

[20] YE X H， YU F， CURIONI M， et al. Corrosion resistance of graphene directly and locally grown on bulk nickel substrate by laser irradiation[J]. Rsc Advances， 2015， 5(45):35 384-35 390.

[21] CHAE S J， Güneş F， KIM K K， et al. Synthesis of largearea graphene layers on polynickel substrate by chemical vapor deposition: wrinkle formation[J]. Advanced Materials，2009， 21(22): 2 328-2 333.

[22] 叶晓慧. 激光快速原位制备石墨烯及其耐腐蚀性研究[D]. 北京: 清华大学， 2015.YE X H， Rapid Laser In-situ Growth of Grapheneand Its Anti-corrosion Performance[D]. Beijing: Tsinghua University， 2015.

[23] 王矜奉. 固体物理教程[M]. 济南: 山东大学出版社，2013: 140-148.WANG J F.Solid State Physics Course[M]. Jinan: Shandong University Press， 2013: 140-148.

Options

文章导航

模态框（Modal）标题

摘要

本文引用格式

Abstract

参考文献