难熔金属表面高温防护涂层抗热震性能研究现状
(1. 西安石油大学材料科学与工程学院,陕西西安710065;2. 西北有色金属研究院,陕西西安710016;
3. 西安理工大学材料科学与工程学院,陕西西安710048)
汪欣(1987-),博士,正高级工程师,主要从事金属的高温腐蚀与防护研究,电话:029-86283410,E-mail: wangx@alum.imr.ac.cn;
刘艳明(1988-),博士,副教授,主要从事金属表面防护涂层与技术研究,电话:029-88382536,E-mail: ymliu10s@alum.imr.ac.cn
收稿日期: 2023-10-25
修回日期: 2023-11-17
录用日期: 2023-12-10
网络出版日期: 2024-03-19
基金资助
国家自然科学基金面上项目(52071274);陕西省重点研发计划一般项目(2023-YBGY-442);陕西省自然科学基础研究计划青年项目(2022JQ-400)资助
Research Status on the Thermal Shock Resistance of High-Temperature
(1. School of Materials Science and Engineering, Xi’an Shiyou University, Xi’an 710065, China;
2. Northwest Institute for Non-Ferrous Metal Research, Xi’an 710016, China; 3. School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China)
WANG Xin(1987-), Ph.D., Senior Engineer, Research Focus: High Temperature Corrosion and Protection of Metals, Tel.: 029-86283410, E-mail: wangx@alum.imr.ac.cn;
LIU Yanming (1988-), Ph.D., Associate Professor, Research Focus: Protective Coatings and Technologies on Metal Surface, Tel.: 029-88382536, E-mail: ymliu10s@alum.imr.ac.cnReceived date: 2023-10-25
Revised date: 2023-11-17
Accepted date: 2023-12-10
Online published: 2024-03-19
Supported by
National Natural Science Foundation of China (52071274); Key Research and Development Program of Shaanxi, China (2023-YBGY-442); Natural Science Basic Research Program of Shaanxi (2022JQ-400)
梁浩然, 刘艳明, 赵科遥, 汪欣 . 难熔金属表面高温防护涂层抗热震性能研究现状[J]. 材料保护, 2024 , 57(3) : 1 -14 . DOI: 10.16577/j.issn.1001-1560.2024.0051
Due to their excellent high-temperature strength, good processing plasticity and corrosion resistance, refractory metals and their alloys are extensively utilized in the aviation, aerospace and nuclear industries, serving as important high-temperature structural materials. However, their susceptibility to oxidation often causes serious oxidation before reaching service temperatures, leading to rapid failure. High performance high-temperature protective coatings are essential for maintaining the performance of these refractory alloy materials at present. However, the actual service conditions of high-temperature protective coatings on surfaces of refractory metals and their alloy are very harsh, often accompanied by strong thermal shock, which is an important reason for coating failure. Therefore, a high-temperature protective coating on refractory metals must have excellent constant temperature oxidation resistance and good thermal shock resistance. In this paper, the thermal shock failure mechanism of high-temperature protective coatings on the surfaces of refractory metals was reviewed, and the key parameters affecting the coatings’ thermal shock resistance were discussed. The research status of the thermal shock resistance of three main coating systems, including silicides, metals and composite coatings on the surface of refractory metals, was expounded. Additionally, the modification methods and their improvement effects, such as optimizing the coating structure, adding ceramic particles and designing composite coatings to improve the thermal shock resistance of coatings, were reviewed. Finally, the future development direction of high-temperature protective coatings for refractory metals was prospected from three aspects: reducing the mismatch of thermal expansion coefficient between the coating and the substrate, improving the interface bonding performance between the substrate and coating and designing composite gradient coatings.
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