马氏体不锈钢表面DLC涂层研究进展

黄腾龙, 张树玲, 武帅政, 郭栋, 崔宁, 孙巍, 丁文捷, 郭峰

doi:10.16577/j.issn.1001-1560.2023.0022

材料保护 >

2023 , Vol. 56 >Issue 1: 146 - 152

DOI: https://doi.org/10.16577/j.issn.1001-1560.2023.0022

综述

马氏体不锈钢表面DLC涂层研究进展

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1. 青岛理工大学机械与汽车工程学院，山东青岛 266520； 2. 宁夏大学机械工程学院，宁夏银川 750001

张树玲(1980-)，博士，副教授，主要研究方向为涂层制备及摩擦磨损性能研究，电话:17861420579，E-mail:Slzhang1299＠163.com

收稿日期: 2022-07-22

修回日期: 2022-08-25

录用日期: 2022-09-16

网络出版日期: 2023-07-26

基金资助

国家自然科学基金(51861031)资助；

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Research Progress of DLC Coating on Martensitic Stainless Steel

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1. School of Mechanical and Automotive Engineering， Qingdao University of Technology， Qingdao 266520， China；2. School of Mechanical Engineering， Ningxia University， Yinchuan 750001， China

Received date: 2022-07-22

Revised date: 2022-08-25

Accepted date: 2022-09-16

Online published: 2023-07-26

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摘要

马氏体不锈钢表面沉积类金刚石(Diamond-like Carbon, DLC)薄膜提高了材料的耐磨性和耐腐蚀性。但由于马氏体基体与DLC涂层热膨胀系数和弹性模量不匹配以及界面原子的亲和性能差等因素,使得DLC涂层与马氏体基体间界面结合强度不够,存在涂层厚度有限等问题,从而限制了DLC涂层的进一步使用。针对以上不足,综述了国内外学者为提高马氏体不锈钢表面沉积DLC涂层的膜基结合力、耐蚀性所采取的有效措施和结果,主要包括基体表面氮化处理、优化工艺参数、设计一层和多层过渡层结构来缓和DLC涂层与马氏体基体结合力和耐蚀性的问题。最后,展望了马氏体不锈钢表面制备DLC防护涂层的发展趋势。

关键词： 马氏体不锈钢; 类金刚石涂层; 磨损性能; 结合性能; 耐蚀性能

本文引用格式

黄腾龙, 张树玲, 武帅政, 郭栋, 崔宁, 孙巍, 丁文捷, 郭峰 . 马氏体不锈钢表面DLC涂层研究进展[J]. 材料保护, 2023 , 56(1) : 146 -152 . DOI: 10.16577/j.issn.1001-1560.2023.0022

Abstract

The deposition of diamond-like carbon(DLC) coating on the surface of martensitic stainless steel improves the wear properties and corrosion properties of the material. However, as the thermal expansion coefficients and elastic moduli of the martensitic stainless steel and the DLC coating are not matched and the affinity of the interface atoms is poor, the bonding force between the DLC coating and the martensitic stainless steel is insufficient and the thickness of the coating is limited. As a result, the application of the coating is also limited. In view of the above deficiencies, the effective measures and achievements made by domestic and foreign scholars to improve the adhesion and corrosion resistance of DLC coating deposited on the surface of martensitic stainless steel were summarized. The measures mainly included nitriding treatment of the surface of martensitic stainless steel, optimizing process parameters, and designing one-layer and multi-layer transition layer structures to alleviate the problems of corrosion resistance and bonding force between DLC coating and martensitic stainless steel. Finally, the development trend of preparation of DLC protective coating on martensitic stainless steel surface was prospected.

Key words： martensitic stainless steel; DLC; wear properties; bonding properties; corrosion properties

参考文献

[ 1] 杨志勇，刘振宝，梁剑雄，等. 马氏体时效不锈钢的发展[J]. 材料热处理学报， 2008(4): 1-7.YANG Z Y， LIU Z B， LIANG J X， et al. Development of maraging stainless steel[J]. Journal of Material Heat Treatment， 2008(4):1-7.

[ 2] ABDELRAHMAN F， TATSUHIKO A. Nitrogen Supersaturation Process in the AISI420 Martensitic Stainless Steels by Low Temperature Plasma Nitriding[J]. Isij International，2018， 58(3): 401-407.

[ 3] 卫中山，左敦稳. 类金刚石膜的制备及应用[J]. 航空精密制造技术， 2004(1): 20-23.WEI Z S， ZUO D W. Preparation and application of diamond-like carbon films[J]. Aeronautical Precision Manufacturing Technology， 2004(1): 20-23.

[ 4] KOVACI H， BARAN O， BAYRAK O， et al. Influence of plasma nitriding treatment on the adhesion of DLC films deposited on AISI 4140 steel by PVD magnetron sputtering[J]. Journal of Adhesion Science and Technology， 2017，31(18): 2 015-2 027.

[ 5] DALIBON E L， BRUHL S P， TRAVA-AIROLDI V J，et al. Hard DLC coating deposited over nitridedmartensitic stainless steel: analysis of adhesion and corrosion resistance[J]. Journal of Materials Research，2016，31(22):3 549-3 556.

[ 6] RAJAK D K， KUMAR A， BEHERA A， et al. Diamond-Like Carbon (DLC) Coatings: Classification， Properties，and Applications[J]. Applied Sciences - Basel，2021， 11(10): 2-20.

[ 7] 张佳佳，何俊宽，徐子钦，等. 类金刚石薄膜在橡胶表面改性中的研究进展[J]. 合成橡胶工业， 2015， 38(1):74-78.ZHANG J J， HE J K， XU Z Q， et al. Research progress of diamond-like carbon films in rubber surface modification[J]. Synthetic Rubber Industry， 2015， 38(1): 74-78.

[ 8] 赖起邦. 类金刚石薄膜的制备和光学性质研究[D]. 厦门: 厦门大学， 2008.LAI Q B. Preparation and optical properties of diamond-like carbon films [D]. Xiamen: Xiamen University， 2008.

[ 9] MAHMUD K A， KALAM M A， MASJUKI H H， et al. An updated overview of diamond-like carbon coating in tribology[J]. Critical Reviews in Solid State and Materials Sciences，2015，40(2):1-29.

[10] PRAWER S， NUGENT K W， LIFSHITZ Y， et al. Systematic variation of the Raman spectra of DLC films as a function of sp2:sp3 compositionDiamond Related Materials[J].Diamond Related Materials， 1996， 5(3-5): 433-438.

[11] 张敏，程发良，姚海军，等. 类金刚石膜的性质和制备及应用[J]. 表面技术， 2006(2): 4-6.ZHANG M， CHENG F L， YAO H J， et al. Properties，preparation and application of diamond - like carbon films[J]. Surface Technology， 2006(2): 4-6.

[12] 吴雁，李艳峰，张而耕，等. PVD 涂层技术制备类金刚石薄膜及性能研究综述[J]. 表面技术， 2016， 45(8):115-123.WU Y， LI Y F， ZHANG E G， et al. Synthesis and Properties of Diamond Like Carbon Films by PVD Coating Technology[J]. Surface Technology， 2016， 45(8): 115-123.

[13] 张碧云，曲燕青，谢红梅，等. 类金刚石膜的制备技术及应用领域概况[J]. 表面技术， 2007(3): 70-73.ZHANG B Y， QU Y Q， XIE H M， et al. Preparation technology and application field of diamond-like carbon films[J]. Surface Technology， 2007(3): 70-73.

[14] 郝甜妹. DLC 复合涂层刀具的力学性能及切削性能研究[D]. 济南: 齐鲁工业大学， 2020.HAO T M. Study on Mechanical and Cutting Properties of DLC Composite Coating Tools[D]. Jinan: Qilu University of Technology， 2020

[15] 胡凯，武明雨，李运刚，等. 马氏体不锈钢的研究进展[J]. 铸造技术， 2015， 36(10): 2 394-2 400.HU K， WU M Y， LI Y G， et al. Research Progress of Martensitic Stainless Steel[J]. Foundry Technology， 2015， 36(10): 2 394-2 400.

[16] DERAZKOLA H A， GIL E G， MURILLO-MARRODAN A，et al. Review on Dynamic Recrystallization of Martensitic Stainless Steels during Hot Deformation: Part I-Experimental Study[J]. Metals， 2021， 11(4): 572.

[17] 李云光. 不锈钢表面处理方法综述[J]. 冶金与材料，2019， 39(5): 142-143.LI Y G. Summary of surface treatment methods of stainless steel[J]. Metallurgy and Materials，2019，39(5):142-143.

[18] STRMCNIK E， MAJDIC F， KALIN M. Water-lubricated behaviour of AISI 440C stainless steel and a DLC coating for an orbital hydraulic motor application[J]. Tribology International， 2019， 131: 128-136.

[19] 彭定文，忽梦磊，刘豪杰，等. 304 不锈钢表面预处理对沉积CrMoN 涂层性能的影响[J]. 机械工程材料， 2021，45(1): 50-58.PENG D W， HU M L， LIU H J， et al. Effect of Surface Pretreatment of 304 Stainless Steel on Properties of Deposited CrMoN Coatings[J]. Mechanical Engineering Materials，2021， 45(1): 50-58.

[20] 邓兴瑞，冷永祥，孙鸿，等. 类金刚石薄膜在不锈钢表面结合强度及耐腐蚀性研究[J]. 功能材料， 2009， 40:1 009-1 012.DENG X R， LENG Y X， SUN H， et al. Study on bonding strength and corrosion resistance of diamond - like carbon films on stainless steel[J]. Functional Materials，2009，40:1 009-1 012.

[21] TYAGI A， WALIA R S， MURTAZA Q， et al. A critical review of diamond like carbon coating for wear resistance applications[J]. International Journal of Refractory Metals and Hard Materials， 2019， 78: 107-122.

[22] 冷永祥，孙永春，孙鸿，等. 沉积温度对脉冲真空弧源沉积类金刚石薄膜性能的影响[J]. 机械工程学报，2004: 20-23.LENG Y X， SUN Y C， SUN H， et al. Effect of deposition temperature on properties of diamond-like carbon films deposited by pulsed vacuum arc source[J]. Journal of Mechanical Engineering， 2004: 20-23.

[23] 吴志猛. 类金刚石膜的制备与特性研究[D]. 阜新: 辽宁工程技术大学， 2002.WU Z M. Preparation and properties of diamond-like carbon films [D]. Fuxin: Liaoning University of Engineering and Technology， 2002.

[24] ZHANG Y K， CHEN D X， DENG H Y， et al. DLC (H)coated 13Cr SMSS by high-pulsed power CVD technique[J]. Surface Engineering， 2021， 37(8): 1 012-1 019.

[25] 孙丽丽，张栋，陈仁德，等. 不锈钢表面沉积DLC 膜的结构和性能[J]. 材料研究学报， 2014， 28: 697-702.SUN L L， ZHANG D， CHEN R D， et al. Structure and Properties of DLC Films Deposited on Stainless Steel[J].Journal of Materials Research， 2014， 28: 697-702.

[26] 李红轩，徐洮，陈建敏，等. 预处理对不锈钢表面沉积类金刚石薄膜的影响[J]. 电子显微学报， 2003(6):545-546.LI H X， XU T， CHEN J M， et al. Effect of pretreatment on diamond-like carbon films deposited on stainless steel[J].Journal of Electronic Microscopy， 2003(6): 545-546.

[27] DALIBON E L， CHARADIA R， CABO A， et al. Evaluation of the mechanical behaviour of a DLC film on plasma nitrided AISI 420 with different surface finishing[J]. Surface Coatings Technology， 2013， 235: 735-740.

[28] LOPEZ R，MENENDEZ M，FERNANDEZ C，et al. The Influence of Carbon Coatings on the Functional Properties of X39Cr13 and 316LVM Steels Intended for Biomedical Applications[J]. Metals， 2019， 9(8): 815.

[29] 胡芳，代明江，林松盛，等. 清洗预处理对手表外观件表面镀类金刚石薄膜性能的影响[J]. 电镀与涂饰，2011， 30(3): 43-45.HU F， DAI M J， LIN S S， et al. Effect of cleaning pretreatment on properties of diamond-like carbon films on watch surface[J]. Electroplating and Painting， 2011， 30(3):43-45.

[30] 李杨，何永勇，朱宜杰，等. 2Cr13 马氏体不锈钢活性屏离子渗氮技术[J]. 金属热处理，2017，42(5):163-167.LI Y， HE Y Y， ZHU Y J， et al. Ion Nitriding Technology with Active Screen for 2Cr13 Martensitic Stainless Steel[J].Metal Heat Treatment， 2017， 42(5): 163-167.

[31] DALIBON E L， PECINA J N， CABO A， et al. Fretting wear resistance of DLC hard coatings deposited on nitrided martensitic stainless steel[J]. Journal of Materials Research and Technology， 2019， 8(1): 259-266.

[32] 刘一奇，韩克昌，林国强，等. 等离子体增强电弧离子镀1Cr17Ni2 不锈钢表面氮化/DLC 涂层复合改性研究[J].真空科学与技术学报， 2017， 37(1): 100-105.LIU Y Q， HAN K C， LIN G Q， et al. Study on Composite Modification of Nitriding/DLC Coating on 1Cr17Ni2 Stainless Steel Surface by Plasma Enhanced Arc Ion Plating[J].Journal of Vacuum Science and Technology， 2017， 37(1):100-105.

[33] FU Y， WEI J， BATCHELOR A W， et al. Some considerations on the mitigation of fretting damage by the application of surface-modification technologies[J]. 2000， 99(1-3):231-245.

[34] 苗树翻，严一心，杭凌侠，等. 不锈钢(3Cr13)镀类金刚石薄膜的研究[J]. 西安工业大学学报， 2006(2):103-106.MIAO S F， YAN Y X， HANG L X， et al. Study on Diamond Like Carbon Films Deposited on Stainless Steel(3Cr13)[J]. Journal of Xi’an University of Technology，2006(2): 103-106.

[35] 崔砚，柳文涛，闫春和，等. 沉积含Si 过渡层对于不锈钢上沉积的DLC 薄膜的性能影响[J]. 导航与控制，2014， 13(4): 56-61.CUI Y， LIU W T， YAN C H， et al. Effect of Si containing transition layer on properties of DLC films deposited on stainless steel[J]. Navigation and Control， 2014， 13(4):56-61.

[36] 郭军霞，陈秋龙，蔡珣，等. DLC 多层膜对9Cr18 微动磨损性能的影响[J]. 上海交通大学学报， 2002， 36(1):24-27.GUO J X， CHEN Q L， CAI X， et al. Effect of DLC Multilayer on Fretting Wear Properties of 9Cr18[J]. Journal of Shanghai Jiaotong University， 2002， 36(1): 24-27.

[37] 周顺，严一心. 脉冲真空电弧离子镀在不锈钢上沉积类金刚石薄膜的研究[J]. 真空， 2005(4): 15-18.ZHOU S， YAN Y X. Study on diamond-like carbon films deposited on stainless steel by pulsed vacuum arc ion plating[J]. Vacuum， 2005(4): 15-18.

[38] DALIBON E L， MOREIRA R D， GUITAR M A， et al. Influence of the substrate pre-treatment on the mechanical and corrosion response of multilayer DLC coatings[J]. Diamond and Related Materials， 2021， 118: 108 507.

[39] RADI P A， VIEIRA A， MANFROI L， et al. Tribocorrosion and corrosion behavior of stainless steel coated with DLC films in ethanol with different concentrations of water[J].Ceramics International， 2019， 45(7): 9 686-9 693.

[40] 黄桂芳，周灵平，李绍禄，等. 类金刚石(DLC)膜对2Crl3 不锈钢耐蚀性能的影响[J]. 表面技术， 2002(1):9-11.HUANG G F，ZHOU L P，LI S L，et al. Effect of diamondlike carbon (DLC) film on corrosion resistance of 2Crl3 stainless steel[J]. Surface Technology， 2002(1): 9-11.

[41] 奚运涛，刘道新，韩栋，等. 离子渗氮AISI 420 马氏体不锈钢耐蚀行为研究[J]. 材料热处理学报， 2007(5):109-114.XI Y T， LIU D X， HAN D， et al. Study on Corrosion Resistance of Ion Nitrided AISI 420 Martensitic Stainless Steel[J]. Journal of Material Heat Treatment， 2007 (5):109-114.

[42] Dalibón E L， PECINA J N， MOSCATELLI M N， et al. Mechanical and Corrosion Behaviour of DLC and TiN Coatings Deposited on Martensitic Stainless Steel[J]. Journal of Bioand Tribo-Corrosion， 2019， 5(2): 2-9.

[43] LEPICKA M， GRADZKA-DAHLKE M. Surface Modification of AISI 440B Stainless Steel and its Influence on Surgical Drill Bits Performance[J]. Archives of Metallurgy and Materials， 2016， 61(3): 1 071-1 077.

[44] 王立达. 不锈钢表面掺硅类金刚石膜的制备、结构及性能[D]. 大连: 大连理工大学， 2005.WANG L D. Preparation， structure and properties of silicon doped diamond-like carbon films on stainless steel [D].Dalian: Dalian University of Technology， 2005.

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