Email Alert  RSS
试验研究

2205和316L不锈钢在钾钠混合熔盐中的腐蚀行为

展开
  • 1四川轻化工大学材料科学与工程学院; 2材料腐蚀与防护四川省重点实验室

网络出版日期: 2025-07-10

Corrosion Behavior of 2205 and 316L Stainless Steel in Potassium - Sodium Mixed Molten Salt

Expand
  • 1.School of Materials Science and Engineering, Sichuan University of Science and Engineering, Zigong 643000, China; 2.Material Corrosion and Protection Key Laboratory of Sichuan Province, Zigong 643000, China

Online published: 2025-07-10

摘要

为了研究不同种类不锈钢在混合熔盐中的高温腐蚀行为,在不同温度的钾钠混合熔盐(KCl+Na2SO4+K2SO4)中通过对2205双相不锈钢和316L不锈钢进行不同时长的静态腐蚀试验,研究了2种材料的物相组成以及表面腐蚀形貌、微区成分和腐蚀动力学曲线。结果表明:2种材料均发生了氧化腐蚀,它们都具有相似的抛物线腐蚀动力学特征,随腐蚀时间的延长,单位面积内腐蚀增重先快速增长后缓慢增长。在600 ℃和650 ℃高温腐蚀24 h后,2205双相不锈钢和316L不锈钢有类似的高温腐蚀规律,质量损失分别达到5 mg/cm2左右和8 mg/cm2左右;在700 ℃下316L不锈钢的腐蚀速率明显低于2205双相不锈钢,这是由于在钢表面较快地形成了NiCr2O4、NiFe2O4和NiO的腐蚀产物层,它们可以有效地减缓腐蚀速率,从而对基体起到了良好的保护作用。

本文引用格式

潘冬梅, 钟强, 罗宏 . 2205和316L不锈钢在钾钠混合熔盐中的腐蚀行为[J]. 材料保护, 2021 , 54(9) : 25 . DOI: 10.16577/j.cnki.42-1215/tb.2021.09.005

Abstract

In order to study the high temperature corrosion behavior of different types of stainless steel in mixed molten salt, different-duration static immersion corrosion experiments were conducted on 2205 duplex stainless steel and 316L stainless steel in potassium-sodium mixed molten salt(KCl +Na2SO4+K2SO4)at different temperatures, and the phase composition, surface corrosion morphology, micro-area composition and corrosion kinetic curve of the two materials were studied.Results showed that oxidation corrosion occurred for the two materials, and they both had similar parabolic corrosion kinetic characteristics, the corrosion mass rapidly increased and then slowly increased in unit area with the increasing corrosion time.After the high temperature corrosion at 600 ℃ and 650 ℃ for 24 h, 2205 duplex stainless steel and 316L stainless steel had similar high temperature corrosion laws, and the mass loss of the two steels reached about 5 mg/cm2 and 8 mg/cm2, respectively.The corrosion rate of 316L stainless steel was significantly lower than that of 2205 duplex stainless steel at 700 ℃, which was due to the rapid formation of corrosion product layers of NiCr2O4, NiFe2O4 and NiO on the steel surface.These corrosion products could effectively slow down the corrosion rate, thus presenting a good protective effect on the substrate.
文章导航

/