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石墨烯机油改进剂的制备及耐磨性能分析

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  • 辽宁科技大学材料与冶金学院
滕莹雪(1979-),副教授,主要研究方向为纳米材料制备及其应用,E - mail: tengyingxue@21cn.com

收稿日期: 2022-01-23

  修回日期: 2022-02-21

  录用日期: 2022-03-28

  网络出版日期: 2024-01-09

基金资助

国家自然科学基金项目(52074149);辽宁省教育厅项目 (2020LNZD07);国家自然基金联合项目(U1860112);辽宁省大学生创新创业计划(S202110146063)资助

Preparation and Wear Resistance Analysis of Graphene Engine Oil Improver

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  • School of Materials and Metallurgy, Liaoning University of Science and Technology, Anshan 114051, China

Received date: 2022-01-23

  Revised date: 2022-02-21

  Accepted date: 2022-03-28

  Online published: 2024-01-09

摘要

 为提高石墨烯在机油中的分散性,采用原位还原的方法,省略氧化石墨烯的还原、冷冻干燥及研磨成粉等复杂工序,节约生产成本,利用基础油自身的还原性将氧化石墨烯直接在基础油中还原,制成尺寸细小、分散均匀的石墨烯发动机机油改进剂。同时,在氧化石墨烯机油改进剂的制备过程中,在对氧化石墨烯离心洗涤的后半程创新性地采用无水乙醇洗涤,大幅度提高了石墨烯在基础油中的分散度;并且在氧化石墨烯的还原过程中,选择维生素C做为还原引发剂,具有优良的环保性。在MS - T3000摩擦磨损仪上进行摩擦磨损测试,结果发现:石墨烯纳米颗粒作为润滑油添加剂,在附着物表面能观察到石墨烯典型的片层结构和卷曲形貌,说明石墨烯的加入产生了“微型球轴承效应”,起到了很好的固体润滑作用,大量的石墨烯附着于金属表面,减少了金属表层硬质相的脱落,与机油一起保护了金属的表面,进而可以明显提高机油的摩擦磨损性能,在降低汽车发动机的磨损方面有较为显著的功效。

本文引用格式

陈浩铭, 刘宏宇, 张喜庆, 郭菁, 滕莹雪 . 石墨烯机油改进剂的制备及耐磨性能分析[J]. 材料保护, 2022 , 55(6) : 113 -119 . DOI: 10.16577/j.issn.1001-1560.2022.0164

Abstract

In order to improve the dispersibility of graphene in engine oil, the in - situ reduction method was adopted, so the complicated processes such as reduction of graphene oxide, freeze - drying and grinding operation to obtain powder were omitted, and the production cost was cut. The graphite oxide was reduced with the help of the reducibility of the base oil to produce a fine - sized, uniformly dispersed graphene engine oil improver. Furthermore, in the preparation process of the graphene oxide engine oil improver, anhydrous ethanol was used to wash the graphene oxide in the second half of the centrifugal washing process of graphene oxide, which greatly improved the dispersion of the graphene in the base oil. In the reduction process of graphene oxide, vitamin C was used as the reduction initiator, making the process environmentally friendly. Results obtained from the friction and wear test carried out on the MS - T3000 friction and wear instrument showed that when the graphene nanoparticle used as lubricant additive, the typical sheet structure and curl morphology of graphene could be observed on the surface of the attached object, indicating that "miniature ball bearing effect" was realized due to the addition of graphene, and thus a good solid lubrication effect was obtained. A large amount of graphene attaching to the metal surface reduced the shedding of the hard phases of the metal surface, protected the metal surface together with the engine oil and significantly improved the friction and wear properties of engine oil, therefore, showed significant effect on reducing the wear on automobile engines.
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