铜-石墨自润滑材料与不同表面处理的对磨件配副的摩擦学行为研究

曹爱军, 井慧哲, 刘代平, 徐秀芳, 程祥勋, 范克龙, 马富存, 朱衍顺, 赵泽翔

doi:10.16577/j.issn.1001-1560.2025.0007

材料保护 >

2025 , Vol. 58 >Issue 1: 64 - 74

DOI: https://doi.org/10.16577/j.issn.1001-1560.2025.0007

研究论文

铜-石墨自润滑材料与不同表面处理的对磨件配副的摩擦学行为研究

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¹山东豪迈机械科技股份有限公司； ²山东省轮胎模具关键技术重点实验室

赵泽翔(1989－)，高级工程师，硕士，主要研究方向为轮胎模具摩擦、磨损，电话:15288821900，E-mail: mjyflzhl＠himile.com

收稿日期: 2024-07-08

修回日期: 2024-08-12

录用日期: 2024-08-15

网络出版日期: 2025-02-28

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Research on the Tribological Behavior of Copper-Graphite Self-Lubricating Material Paired with the Counterparts with Different Surface Treatments

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(1.Himile Mechanical Science and Technology (Shandong) Co.， Ltd.， Gaomi 261500， China；2.Shandong Provincial Key Laboratory of Core Tire Mold Technology， Gaomi 261500， China)

ZHAO Zexiang(1989－)， Senior Engineer， Research Focus: Friction and Wear of Tire Mold， Tel.:15288821900，E-mail: mjyflzhl＠himile.com

Received date: 2024-07-08

Revised date: 2024-08-12

Accepted date: 2024-08-15

Online published: 2025-02-28

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摘要

合理的配副能够提高轮胎活络模具摩擦副的服役寿命，但目前缺乏对轮胎活络模具实际摩擦工况下配副的研究，针对此现状开展了研究，为合理选择轮胎活络模具的摩擦副提供指导。为模拟轮胎活络模具实际摩擦工况，自主研发了试验设备，分别采用激光淬火试块、Ni-P 合金试块、QPQ(氮碳氧复合处理技术)试块与铜-石墨自润滑材料配副，对比了3 组摩擦副的摩擦系数、磨损量、磨损后表面以及磨屑的形貌和成分，阐明了摩擦磨损的机理。结果表明:与铜-石墨自润滑材料配副，激光淬火试块和QPQ 试块的摩擦系数曲线平缓稳定，而Ni-P 合金试块的摩擦系数曲线波动范围较大，平均摩擦系数由小到大依次为激光淬火试块<Ni-P 合金试块<QPQ 试块；在摩擦过程中，激光淬火试块不断以磨粒磨损的形式损耗，QPQ 试块基本无磨损，表面仅受轻微的磨粒磨损，而Ni-P 合金试块表面无损伤；与激光淬火试块配副，铜-石墨自润滑材料以磨粒磨损、黏着磨损、疲劳磨损的形式损伤，在Ni-P合金/铜-石墨摩擦副中，铜-石墨自润滑材料主要以黏着磨损的形式损耗，而与QPQ 试块配副，铜-石墨自润滑材料则以磨粒磨损的形式不断磨损，磨损量从小到大排列顺序依次为QPQ 试块<激光淬火试块<Ni-P 合金试块。综合摩擦副的磨损情况，与铜-石墨自润滑材料配副，QPQ 试块最为适用，服役寿命最长。

关键词： 激光淬火; Ni-P 合金; QPQ (氮碳氧复合处理技术); 铜-石墨自润滑材料; 摩擦磨损

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曹爱军, 井慧哲, 刘代平, 徐秀芳, 程祥勋, 范克龙, 马富存, 朱衍顺, 赵泽翔 . 铜-石墨自润滑材料与不同表面处理的对磨件配副的摩擦学行为研究[J]. 材料保护, 2025 , 58(1) : 64 -74 . DOI: 10.16577/j.issn.1001-1560.2025.0007

Abstract

Reasonable matching can improve the service life of the friction pair of tire active molds， but there is a lack of research on the matching of tire active molds under actual friction conditions.In view of this situation，a study was conducted to provide guidance for the rational selection of friction pairs for tire active molds.To simulate the actual friction conditions of tire active molds，test equipment was independently developed.Laser quenching test blocks， Ni-P alloy test blocks and QPQ (nitrogen-carbon-oxygen composite treatment technology) test blocks were respectively employed to be paired with the copper-graphite self-lubricating material.Additionally， the friction coefficient， wear loss，morphology and composition of the worn surface and debris of the three groups of friction pairs were compared， and the mechanism of friction and wear was explained.Results showed that when paired with copper-graphite self-lubricating material， the friction coefficient curves of laser quenching test block and QPQ test block were gentle and stable，while the friction coefficient curve of Ni-P alloy test block had a large fluctuation range.Moreover， the order of the average friction coefficient from small to large was laser quenching test block < Ni-P alloy test block <QPQ test block.During the friction process，the laser quenching test blocks were constantly worn out in the form of abrasive wear，the QPQ test blocks were basically not worn out，and the surface was only slightly worn out by abrasive wear，while the Ni-P alloy test blocks had no surface damage.When paired with laser quenching test blocks，the copper-graphite self-lubricating material was damaged in the form of abrasive wear，adhesive wear and fatigue wear.In the Ni-P alloy/copper-graphite friction pair， the copper-graphite self-lubricating material was mainly damaged in the form of adhesive wear.In contrast， the copper-graphite self-lubricating material was continuously worn in the form of abrasive wear when paired with QPQ test blocks.The order of the wear amount from small to large was QPQ test block < laser quenching test block < Ni-P alloy test block.Considering the wear of the friction pair， the QPQ test block was the most suitable for pairing with copper-graphite self-lubricating material and had the longest service life.

Key words： laser quenching; Ni-P alloy; QPQ(nitrogen-carbon-oxygen composite treatment technology); copper-graphite self-lubricating material; friction and wear

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