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Corrosion and Protection of Light Alloy Column
Editor: QI Jiantao
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  • LI Yizhe, BIAN Guixue, HUANG Hailiang, ZHANG Yong, WANG Xi
    Materials Protection. 2023, 56(12): 1-6. https://doi.org/10.16577/j.issn.1001-1560.2023.0281
    The natural environment spectrum and equivalent conversion relationship are important input parameters for the complication of aircraft acceleration test environment spectrum. Due to the large discrete nature of environmental data and the small number of sample data, traditional parameter estimation methods are no longer suitable for compilation of natural environment spectra. Based on the idea of small sample parameter estimation, this paper established a high confidence natural environment spectrum through Bootstrap data expansion and grey confidence interval estimation. Subsequently, electrochemical tests were carried out on 7050 aluminum alloy and TC18 titanium alloy, which were typical dissimilar metal connection materials for aircraft, and their equivalent conversion coefficients were calculated at the temperature of accelerated test environment based on the principle of isoelectric quantity. On this basis, the accelerated test environment spectrum of aluminum-titanium alloy joint structure was given, which could provide a reference for the engineering of calendar life assessment of aircraft dissimilar metal joint structure.
  • HUANG Youwang, SUN Xiaoling, YANG Wenjin, CHEN Hui
    Materials Protection. 2023, 56(12): 7-11. https://doi.org/10.16577/j.issn.1001-1560.2023.0282
    To study the feasibility of magnesium alloys used in aerospace vehicles and its corrosion resistance, the polarization data of HTM1 (Aerospace No.1 magnesium alloy) and TC4 (titanium alloy) were firstly measured through electrochemical tests, as well as the impedance data of HTM1 specialized electrophoretic paint. Subsequently, the simulation technology with polarization data, impedance data, aging data and service environment as boundary conditions was utilized to simulate and analyze the corrosion status of different typical ultra strong and heat-resistant magnesium alloy structural components in different service environments (service environment 1 with a salt mist concentration of 0.2 mg/L, and service environment 2 with a salt mist concentration of 2 mg/L) after 5.0, 10.0 and 17.5 a of service, respectively. Results showed that during the service process in service environment 1 and service environment 2, with the extension of service life, the protective performance of the electrophoretic paint decreased, leading to a gradual enhancement of the protective effect of HTM1 on TC4. However, due to the influence of the surface protective layer of HTM1, the protective effect was limited, leading to a certain degree of corrosion of TC4. Meanwhile, the contact area of the titanium magnesium couple in the two structural components was different, resulting in different degrees of protection for TC4. The larger the contact area between the two, the higher the degree of protection for TC4.
  • YU Deshui, LIU Yonghao, ZHAO Guodong, HOU Yan, JIE Dejia, WANG Hanbing, ZHAO Qixin, QI Jiantao
    Materials Protection. 2023, 56(12): 12-18. https://doi.org/10.16577/j.issn.1001-1560.2023.0283
    In recent years, closed circulating water systems in heat exchangers have been developing continuously. During the high-temperature heat exchange process in summer, the external spray system can easily cause scaling and corrosion of the heat exchanger. In order to study the factors affecting the scaling and corrosion of the heat exchanger under different pH and spray conditions of the spray working solution, the experimental methods such as immersion experiments and interval titration methods were designed to simulate the actual working environment. Moreover, the scaling mechanism of the heat exchanger was further clarified through characterization methods such as sample microsurface morphology, mass changes, and electrochemical performance tests. Results showed that under the short-cycle heating titration experiment, the simulated solution with pH=5 was prone to react in a dynamic environment and was prone to scaling in the flat tube. Under the immersion experiment and the long-cycle heating titration experiment, the simulated solution was in the relatively static condition, and the experimental samples were not easy to be scaled. In general, this work enriched the related research on plate heat exchanger fouling and provided a strong basis for future plate heat exchanger fouling and corrosion protection.
  • ZHANG Kai, WANG Xiaojun, GUI Taijiang, ZHU Yongqiang, WANG Hanbing, QI Jiantao
    Materials Protection. 2023, 56(12): 19-24. https://doi.org/10.16577/j.issn.1001-1560.2023.0284
    In order to explore the composition, pH and concentration changes of the antifouling agent zinc pyrithione (ZPT) during the service process of zinc pyrithione-containing self-polishing antifouling coating (ZPT-SPC), and clarify the antifouling mechanism of ZPT-SPC during service, SEM/EDS were employed to explore the changes in cross-sectional micromorphology and composition of coatings before and after polishing. Moreover, the open circuit potential-pH experiment was used to measure the changes in the micro-potential-pH information of paint scratches. The changes in ZPT composition and content on the paint surface during service were explored through Raman spectroscopy. SEM/EDS results showed that the surface became denser, and the Zn element content decreased after polishing. Notably, the Zn content was much greater than the Cu content, which indicated that he ZPT content was much greater than the Cu2O content. In addition, the open circuit potential-pH measurement results showed that the pH value of the ZPT-SPC scratch interface generally exhibited a trend of first decreasing and then increasing, and eventually approached the original pH value. Raman results showed that the ZPT slowly diffused to the outside, which reduced the internal concentration, and the ZPT component transfer occurred inside the antifouling coating, resulting in a more uniform distribution of components. Furthermore, this process could be characterized macroscopically by antifouling agent concentration-color gray correlation model.