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The 14th National Youth Academic Conference on Surface Engineering Column
Editor: ZHANG Guang'an
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  • LI Jincheng, SHI Yeran, HUA Dongpeng, ZHOU Qing, XIA Qiaosheng, CHAI Liqiang, WANG Haifeng, WANG Peng
    Materials Protection. 2025, 58(4): 1-16. https://doi.org/10.16577/j.issn.1001-1560.2025.0055
    Solid lubricating thin film materials play a significant role in aerospace,the nuclear industry and mechanical engineering due to their excellent performance in reducing friction and wear, as well as their good chemical stability and resistance to high temperatures.However,these materials face the challenge of radiation damage in extreme environments, such as space and high-temperature nuclear reactors, which can lead to a significant decrease in material performance, thus affecting their reliability and durability in practical applications.In this paper,three main types of solid lubricating thin films were first introduced, which included two-dimensional layered lubricating films, carbon-based lubricating thin films, and metal-based lubricating thin films.Two-dimensional layered lubricating films,such as graphene and transition metal dichalcogenides,showed ultra-low friction coefficients due to their single or few layers of atomic thickness, achieving a “superlubricating”effect.These materials were not only recognized for their excellent tribological properties but also for their exceptional mechanical strength and chemical inertness, making them potentially valuable for applications in harsh environments, such as nuclear radiation.Carbon-based lubricating thin films, such as hydrogenated amorphous carbon films, graphite, and fullerenes, maintained their lubricating performance in adverse environments due to their diverse allotropes of carbon and physical and chemical properties.Metal-based lubricating thin films, especially silver-based films, were shown to exhibit good lubricating performance in high-temperature and irradiation environments when combined with other solid lubricants.Secondly, the challenges faced by solid lubricating films in irradiation environments were summarized, and an outlook on future research directions in the field of radiation resistance of commonly used solid lubricating films was provided.Five strategies to enhance the radiation resistance of solid lubricating films were further explored:First,thermal annealing treatments were conducted,after which two-dimensional layered lubricating films,such as MoS2,were shown to exhibit fewer defects when subjected to irradiation.Second,doping with radiation-resistant elements was proposed;for example,chromium was introduced into carbon-based lubricating films,effectively improving the tribological stability and durability of DLC materials.The third strategy involved designing multilayer film structures that captured defect atoms through heterointerfaces, effectively improving the tribological performance of metal-based lubricating films.The fourth strategy was to regulate the interfacial area,where the crystal/amorphous interface was found to have higher radiation tolerance.The fifth strategy was to refine the grain size, as grain refinement was shown to effectively improve the radiation resistance of metal-based lubricating films.In conclusion,solid lubricating thin films have great application potential in extreme environments such as space exploration and the nuclear industry.Future research will focus on deeply understanding the impact of irradiation on solid lubricating thin films and developing new strategies to improve their radiation resistance, ensuring that these materials can maintain their excellent lubricating performance in extreme environments.
  • ZHENG Yaxin, FAN Bingcheng, LIU Yi
    Materials Protection. 2025, 58(4): 17-29. https://doi.org/10.16577/j.issn.1001-1560.2025.0056
    Magnesium potassium phosphate cement (MKPC), as a new type of inorganic cementitious material, shows the characteristics of fast setting speed, high early strength, dense structure, and good wear resistance.Employing magnesium potassium phosphate as a binder,modified by additives,mineral admixtures and composite modification methods,metal protective coatings with excellent anti-corrosion properties can be obtained, which are mainly used for corrosion protection of steel surfaces.This paper reviewed the hydration and anti-corrosion mechanisms of MKPC-based coatings, examining the influence of material composition and mix design on their protective performance.In particular,the modification approaches for MKPC-based anti-corrosive coatings were discussed, with their application techniques and performance evaluation methods being comprehensively documented.Furthermore, prospective applications of MKPC-based coatings in corrosion protection were critically evaluated.
  • WANG Jiangang, FAN Yuxing, ZHANG Xin, WANG Yujiang, LUO Wei, WANG Lei, WANG Jingjing
    Materials Protection. 2025, 58(4): 30-39. https://doi.org/10.16577/j.issn.1001-1560.2025.0057
    Diamond-like carbon (DLC) films have drawn considerable attention in various fields due to their excellent lubricating and wearresistant properties.This paper systematically reviewed the research progress of magnetron sputtering technology in DLC film preparation, with emphasis on the regulating mechanisms of process parameters and elemental doping on film performance.Firstly, the effects of key parameters including gas flow ratio, bias voltage and current on the microstructure and tribological properties of DLC films were analyzed: optimizing gas ratios (e.g., Ar/CH4) could regulate the sp2/sp3 bond ratio to reduce the friction coefficient; bias voltage control could balance film hardness and surface defects; current adjustment directly affected the ion flux and sp3 bond stability.Secondly, the doping mechanisms of non-metal(Si, N, F) and metal (Cr, Ti) elements were summarized: Si doping enhanced high-temperature stability and reduced residual stress; N doping promoted graphitic structure formation; F doping passivated surface dangling bonds through C-F bonds; while Cr and Ti incorporation inhibited oxidation through carbide phases and optimized mechanical properties.Finally, the development prospects of DLC film technology were prospected.
  • FU Shuo, XU Aijun, XU Yaxin, ZHU Lijuan, LOU Liyan, LI Wenya
    Materials Protection. 2025, 58(4): 40-47. https://doi.org/10.16577/j.issn.1001-1560.2025.0058
    Titanium alloys exhibit promising application prospects in ultra-deep well drilling.To enhance the surface wear resistance of titanium alloy drill pipes, WC gradient wear-resistant coatings were fabricated using laser cladding technology.The microstructure, phase composition,elemental distribution, mechanical properties, and tribological performance of the gradient coatings were systematically investigated through OM, SEM, EMPA, XRD, hardness tester, friction and wear tester and white light interferometry.Results demonstrated that the gradient coatings primarily consisted of α-Ti,WC,TiC,TixW(1-x) solid solutions,and minor Y2O3.There were interdiffusion layers with a thickness of several tens of micrometers between the gradient coating layers and the bottom layer and substrate, and the metallurgical bonding was formed between the layers, which improved the bonding property of the coating.Meanwhile, the top layer of the gradient coating exhibited 1.45 times higher wear resistance compared to TC4 substrate.Both TC4 substrate and gradient coatings displayed wear mechanisms dominated by adhesive wear and abrasive wear, while the wear resistance of gradient coatings was higher than that of the substrate.
  • XIAO Jialin, CHEN Yunfeng, LI Hao, SUO Xinkun, CAO Jun
    Materials Protection. 2025, 58(4): 48-55. https://doi.org/10.16577/j.issn.1001-1560.2025.0059
    In order to enhance the tribological and anti-corrosion performance of copper alloy bearing bushes in methanol fuel leakage environments, an epoxy resin (EP) coating filled with Ti3AlC2 and B4C was designed and prepared on the surface of CuPb24Sn by liquid spraying method.The corrosion resistance of the composite coating was characterized by electrochemical impedance spectroscopy in a formic acid and methanol mixed solution with a volume ratio of 1:9, while its temperature rise tribological performance and wear mechanisms under complex working conditions (formic acid +methanol +lubricating oil) were investigated through high-frequency reciprocating friction-wear tests.Results showed that the Ti3AlC2- and B4C-filled EP coating exhibited excellent corrosion resistance.Under the formic acid +methanol +lubricating oil condition, the coating’s friction coefficient decreased with rising temperature, whereas its wear rate increased.At 75 ℃, the wear scar became wider than at 25 ℃, with evident ploughing effects observed on the worn surface.Materials Studio software was used for simulation calculation, and it was found that the decrease in shear strength of epoxy resin with increasing temperature was the main reason for the change in wear rate of coating.
  • WANG Yonghong, ZHANG Chunlin, ZHANG Shihan, YU Jianping, LIU Yingfu, JIE Zhiwen
    Materials Protection. 2025, 58(4): 56-69. https://doi.org/10.16577/j.issn.1001-1560.2025.0060
    In order to deeply study the influence of the surfacing current on the microstructure and mechanical properties of FeCoNiAlTi highentropy alloy coatings in the plasma surfacing process parameters, five different surfacing currents (140, 160, 180, 200, 220 A) were used for coating preparation, and the microstructure, hardness, wear resistance and tensile properties of the coatings were evaluated by XRD, OM,SEM, micro-Vickers hardness tester, profilometer, friction wear tester and universal testing machine, respectively.Results showed that the porosity and elemental segregation of the coating were significantly improved with the increase of the surfacing current,but there was no significant effect on the coating phase composition.The coating mainly consisted of the typical FCC solid solution phase and Co3 Ti precipitation phase.When the surfacing current was 180 A, the surface microhardness of the obtained T3 coating was up to 322.77 HV0.2, which was about twice that of the substrate.At the same time, the T3 coating showed the best wear resistance, with a maximum wear depth of only 2.144 μm, an average friction coefficient of 0.362 and the lowest wear rate of 3.83×10-6 mm3/(N·m).In addition, the tensile strength and elongation of the T3 coating were 948 MPa and 26.61%, respectively, showing excellent strength and toughness.
  • LUO Maoliang, ZHANG Xiuju, ZHOU Qiaoyan, KANG Jia, GUO Guangzhao, WANG Jing, LIU Huan
    Materials Protection. 2025, 58(4): 70-77. https://doi.org/10.16577/j.issn.1001-1560.2025.0061
    The low-temperature corrosion problem of the tail flue of a waste incineration plant restricts the safe and stable operation of the incinerator.In this study, for the low-temperature corrosion problem of the dust collector ash hopper of a coastal waste incineration plant, the low-temperature corrosion mechanism under the joint action offlue gas condensed acid liquid and deposited ash was revealed by analyzing the microscopic morphology, elemental composition, crystalline composition, and ionic dissolution characteristics of the corrosion products and the deposited ash on the surface.Results showed that the corrosion products in the hopper primarily consisted of iron oxides, and a large amount of deposited ash rich in alkali metal salts (NaCl, KCl, CaClOH, etc.) adhered to the surface.Under the combined action of condensed acid liquid and deposited ash,the corrosive medium in the dust collector contained ions (Cl,Ca2+,K,Na) that significantly influenced electrochemical corrosion on equipment surfaces.Among them, the Ca2+dissolution concentration reached 0.35 mol/L, accounting for 81.4%of the total cation concentration,and the Cl dissolution concentration reached 0.55 mol/L,accounting for 96.5%of the total anion concentration.The electrochemical impedance spectroscopy test results further indicated that Ca2+and Cl significantly reduced the charge transfer resistance of the electrochemical corrosion reaction, and the two ions were the key ions affecting the corrosion.In general, this study provided guidelines for the design of surface coatings used for low-temperature corrosion protection.
  • WANG Hongyu, WANG Yiyong, WANG Lubin, LIANG Zhipeng
    Materials Protection. 2025, 58(4): 78-89. https://doi.org/10.16577/j.issn.1001-1560.2025.0062
    Enhancing the anti-friction and anti-wear and corrosion resistant properties of mold copper plates holds significant research significance and value for the development and improvement of continuous casting molds.In this study, a Ni-Co/Al2O3 nanocomposite coating was electrodeposited on the surface of a Cu-Cr-Zr alloy substrate with the assistance of ultrasonic during the electroplating process, and the plating bath was formulated by incorporating nano-Al2O3 particles with an average diameter of 20 nm into a sulfamate-based electrolyte system.Subsequently, the composite coating was systematically characterized through friction and wear testing, high-temperature oxidation evaluation,microhardness measurement, adhesion assessment, and corrosion resistance analysis.Results showed that the optimal process parameters were current density of 5 A/dm2, bath temperature of 50 ℃, nano-Al2O3 concentration of 10 g/L, deposition time of 1.00 h, ultrasonic power of 200 W, and mechanical stirring at 500 r/min.Under this process,the Ni-Co/Al2O3 nanocomposite coating exhibited the highest surface microhardness, the finest and most compact structure arrangement, the uniformly dispersed nanoparticles embedded in the metal matrix without obvious agglomeration, and the optimal microscopic morphology.Moreover, the Ni-Co/Al2O3 nanocomposite coating prepared with ultrasonic assistance had excellent high-temperature oxidation resistance at 400 ℃; Compared with Cu-Cr-Zr alloy and Ni-Co alloy coatings, Ni-Co/Al2O3 nanocomposite coating possessed the best anti-friction and anti-wear performance and corrosion resistance